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Menu Groceries Cooking. German Baking Art. Gummy Candies. Licorice Candies. Fizzy Candies. Jelly Sweets. Shortly thereafter, in a limited partnership with the Frankfurt firm Hoechst AG , a factory was built in Kelsterbach , Hessen ; from there, Celcon was produced starting in ,  with Hostaform joining it a year later.
Different manufacturing processes are used to produce the homopolymer and copolymer versions of POM. To make polyoxymethylene homopolymer , anhydrous formaldehyde must be generated.
The formaldehyde is then polymerized by anionic catalysis , and the resulting polymer stabilized by reaction with acetic anhydride. Due to the manufacturing process, large-diameter cross-sections may have pronounced centerline porosity.
The polyoxymethylene copolymer replaces about 1—1. To make polyoxymethylene copolymer , formaldehyde is generally converted to trioxane specifically 1,3,5-trioxane , also known as trioxin.
The co-monomer is typically dioxolane , but ethylene oxide can also be used. Dioxolane is formed by reaction of ethylene glycol with aqueous formaldehyde over an acid catalyst.
Other diols can also be used. Trioxane and dioxolane are polymerized using an acid catalyst, often boron trifluoride etherate , BF 3 OEt 2.
The polymerization can take place in a non-polar solvent in which case the polymer forms as a slurry or in neat trioxane e.
After polymerization, the acidic catalyst must be deactivated and the polymer stabilized by melt or solution hydrolysis to remove unstable end groups.
Stable polymer is melt-compounded, adding thermal and oxidative stabilizers and optionally lubricants and miscellaneous fillers. POM is supplied in a granulated form and can be formed into the desired shape by applying heat and pressure.
The two most common forming methods employed are injection molding and extrusion. Rotational molding and blow molding are also possible.
Typical applications for injection-molded POM include high-performance engineering components e. POM is commonly extruded as continuous lengths of round or rectangular section.
These sections can be cut to length and sold as bar or sheet stock for machining. When supplied as extruded bar or sheet, POM may be machined using traditional methods such as turning, milling, drilling etc.
These techniques are best employed where production economics do not merit the expense of melt processing. The material is free-cutting, but does require sharp tools with a high clearance angle.
The use of soluble cutting lubricant is not necessary, but is recommended. POM sheets can be cut cleanly and accurately using an infrared laser, such as in a CO 2 laser cutter.
Because the material lacks the rigidity of most metals, care should be taken to use light clamping forces and sufficient support for the work piece.
As can be the case with many polymers, machined POM can be dimensionally unstable, especially with parts that have large variations in wall thicknesses.
It is recommended that such features be "designed-out" e. Annealing of pre-machined parts before final finishing is an alternative. A rule of thumb is that in general, small components machined in POM suffer from less warping.
POM is typically very difficult to bond, with the copolymer typically responding worse to conventional adhesives than the homopolymer. Typical etching processes involve chromic acid at elevated temperatures.
DuPont uses a patented process for treating acetal homopolymer called satinizing that creates a surface roughness sufficient for micromechanical interlocking.
There are also processes involving oxygen plasma and corona discharge. Once the surface is prepared, a number of adhesives can be used for bonding.
These include epoxies , polyurethanes , and cyanoacrylates.